HCFO-1233zd

  性质 Properties Symbol Unit Value References
Basic Physical and Chemical Properties CAS注册号 CAS Registry Number CASRN / 102687-65-0 Scifinder
中文名称 Chemical Name / / trans-1-Chloro-3,3,3-trifluoropropene
一氯三氟丙烯
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英文名称 English Name / / trans-HCFO 1233zd,HCFC 1233zd-E Scifinder
组成 Composition / / /
分子式 Molecular Formula / / C3H2ClF3 Scifinder
结构式 Structure Formula / / CF3CH=CHCl Scifinder
相对分子量 Molecular Weight MW / 130.5 Scifinder
物理状态 Physical State / / Gas The acute, genetic, developmental and inhalation toxicology of trans-1-chloro,3,3,3-trifluoropropene (HCFO-1233zd(E)).Drug Chem Toxicol, Early Online: 1–10
气味 Odor / / slight Honeywell MSDS
颜色 Color / / Colorness The acute, genetic, developmental and inhalation toxicology of trans-1-chloro,3,3,3-trifluoropropene (HCFO-1233zd(E)).Drug Chem Toxicol, Early Online: 1–10
熔点 Melting Point mp -107 Honeywell MSDS
沸点 Boiling Point bp 20.8
19
21
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The acute, genetic, developmental and inhalation toxicology of trans-1-chloro,3,3,3-trifluoropropene (HCFO-1233zd(E)).Drug Chem Toxicol, Early Online: 1–10
SynQuest Laboratories MSDS
饱和蒸汽压 Saturated Vapor Pressure(25℃) Psat MPa 0.11759
0.1274
0.106320
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Physical Properties of HCFO-1233zd(E)
Honeywell MSDS
液体密度 Liquid Density(25℃) dl g/cm3 1.312±0.0620
1.29620
2.27
1.273420
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Honeywell MSDS
Honeywell MSDS
Physical Properties of HCFO-1233zd€
气体密度 Vapor Density(25℃, 101.325kPa) dg kg/m3 6.28 OARS
挥发性 Volatility / wt%
蒸发速度 Evaporation Rate(CCl4=1) / /
Critical Properties 临界温度 Critical Temperature Tc 156.6
165.6
processing and properties of polystyrene foamed using hydrofluoroolefins
Physical Properties of HCFO-1233zd€
临界压力 Critical Pressure Pc MPa 3.77
3.772
processing and properties of polystyrene foamed using hydrofluoroolefins
Physical Properties of HCFO-1233zd€
临界体积 Critical Volume Vc cm3/mol
临界密度 Critical Density ρc kg/m3
临界压缩因子 Critical Compressibility Factor Zc /
液体压缩因子 Liquid Compressibility Factor Z /
气体压缩因子 Vapor Compressibility Factor Z /
偏心因子 Acentric Factor ω /
Thermophysical Properties 液体焓 Liquid Enthalpy H kJ/kg
气体焓 Vapor Enthalpy H kJ/kg
液体熵 Liquid Entropy S kJ/kg·K
气体熵 Vapor Entropy S kJ/kg·K
生成焓 Enthalpy of Formation(25℃) ΔfHO kJ/mol
蒸发焓 Enthalpy of Vaporization ΔvH kJ/kg 196.48
194bp
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Honeywell MSDS
液体等压热容 Liquid Isobaric Heat Capacity(25℃) Cp kJ/kg·K
气体等压热容 Vapor Isobaric Heat Capacity(25℃) Cp kJ/kg·K
液体等容热容 Liquid Isochoric heat capacity(25℃) Cv kJ/kg·K
气体等容热容 Vapor Isochoric heat capacity(25℃) Cv kJ/kg·K
Solubility 偶极矩 Dipole Moment μ D
解离常数 Dissociation Constant
清洗能力 KB
水中溶解度 Solubility in Water(23℃) / ppm wt/wt 940
1900000
460
1900
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The acute, genetic, developmental and inhalation toxicology of trans-1-chloro,3,3,3-trifluoropropene (HCFO-1233zd(E)).Drug Chem Toxicol, Early Online: 1–10
Honeywell MSDS
Honeywell MSDS
贝壳松脂丁醇值 Kauri-Butanol Value KB / 25 Honeywell MSDS
辛醇/水分配系数 Octanol/Water Partition Coefficient LogP / 1.468±0.411
2.2
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The acute, genetic, developmental and inhalation toxicology of trans-1-chloro,3,3,3-trifluoropropene (HCFO-1233zd(E)).Drug Chem Toxicol, Early Online: 1–10
Hildabrand溶解度参数 Hildabrand Solubility Parameter δ cal/ml
Other Properties 液体焦耳-汤姆逊系数 Liquid Joule-Thomson Coefficient JT ℃/MPa
气体焦耳-汤姆逊系数 Vapor Joule-Thomson Coefficient JT ℃/MPa
液体粘度 Liquid Viscosity(25℃) η mPa·s 0.489 cP20
0.0605
Honeywell MSDS
Physical Properties of HCFO-1233zd€
气体粘度 Vapor Viscosity(25℃) η mPa·s
液体导热系数 Liquid Thermal Conductivity(25℃) λ mW/m·K
气体导热系数 Vapor Thermal Conductivity(25℃) λ mW/m·K 10.220 Honeywell MSDS
液体介电常数 Liquid Dielectric Constant ε F/m
气体介电常数 Gas Dielectric Constant ε F/m
液体体积电阻系数 Liquid Volume Resistivity(1kHz) ρ Ω·cm
气体体积电阻系数 Gas Volume Resistivity(1kHz) ρ Ω·cm
表面张力 Surface Tension(25℃) γ mN/m 13.320
12.68
Honeywell MSDS
Physical Properties of HCFO-1233zd€
液体声速 Liquid Sound Velocity u m/s
气体声速 Vapor Sound Velocity u m/s
最低灭火浓度 Minimum Extinguishment Concentration MEC %
Atmospheric Effects 臭氧消耗潜能值 Ozone Depletion Potential ODP / ~0 Honeywell MSDS
全球变暖潜能值 Global Warming Potential(100yr) GWP / <5 Honeywell MSDS
大气寿命 Atmospheric Life / yr 0.071 Honeywell MSDS
光化学臭氧合成潜能 photochemica lozone creation potential POCP /
全球温度潜势 global temperature change potential(100yr) GTP / 0 Global Warming Potentials and Radiative Efficiencies of Halocarbons and Related Compounds: A Comprehensive Review, Accepted for publication in Rev. Geophys
Flammability 闪点 Flash Point / -9.5±17.9
None
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Honeywell MSDS
自燃点 Autoignition Point / 80 Honeywell MSDS
燃烧下限 Lower Flammability Limit LFL %vol None Honeywell MSDS
燃烧上限 Upper Flammability Limit UFL %vol None Honeywell MSDS
燃烧热 Heat of Combustion HOC MJ/kg
最小点火能 Minimum Ignition Energy MIE mJ
燃烧速度 Burning Velocity Su cm/s
可燃浓度限值 ASHRAE Flammable Concentration Limit FCL ppm v/v
最大燃烧压力 Maximum Combustion Pressure 105Pa
最大燃烧压力上升速率 Maximum Rate of Pressure Increase During Combustion
Toxicity RTECS号 Registry of Toxic Effects of Chemical Substances® Number / /
接近致死浓度 Approximate Lethal Concentration ALC ppm v/v
半数致死浓度 Lethal Concentration 50% LC50 ppm v/v 120000 The acute, genetic, developmental and inhalation toxicology of trans-1-chloro,3,3,3-trifluoropropene (HCFO-1233zd(E)).Drug Chem Toxicol, Early Online: 1–10
心脏致敏最低作用剂量 Cardiac Sensitization Lowest Observed Effect Level LOEL ppm v/v 25000 The acute, genetic, developmental and inhalation toxicology of trans-1-chloro,3,3,3-trifluoropropene (HCFO-1233zd(E)).Drug Chem Toxicol, Early Online: 1–10
心脏致敏最高无作用剂量 Cardiac Sensitization No Observed Effect Level NOEL ppm v/v
麻醉效应半数作用浓度 Anesthesia Effective Concentration 50% EC50 ppm v/v
麻醉效应最低作用剂量 Anesthesia Lowest Observed Effect Level LOEL ppm v/v
麻醉效应最高无作用剂量 Anesthesia No Observed Effect Level NOEL ppm v/v
28天亚急性吸入毒性 28 Days Subacute Inhalation Toxicity NOEL ppm v/v 50002w
45004w
The acute, genetic, developmental and inhalation toxicology of trans-1-chloro,3,3,3-trifluoropropene (HCFO-1233zd(E)).Drug Chem Toxicol, Early Online: 1–10
90天亚慢性吸入毒性 90 Days Subchronic Inhalation Toxicity NOEL ppm v/v >10000
15,000
The acute, genetic, developmental and inhalation toxicology of trans-1-chloro,3,3,3-trifluoropropene (HCFO-1233zd(E)).Drug Chem Toxicol, Early Online: 1–10
OARS
一年长期吸入毒性 Long Term Inhalation Toxicity (12 month) NOEL ppm v/v
两年长期吸入毒性 Long Term Inhalation Toxicity (24 month) NOEL ppm v/v
立即威胁生命和健康浓度 NIOSH Immediately Dangerous to Life or Health IDLH ppm v/v
缺氧限值 ASHRAE Oxygen Deprivation Limit ODL ppm v/v
急性毒性暴露限值 ASHRAE Acute Toxicity Exposure Limit ATEL ppm v/v
制冷剂浓度限值 ASHRAE Refrigerant Concentration Limit RCL ppm v/v
职业接触限值 ASHRAE Occupational Exposure Limit OEL ppm v/v 300 Honeywell MSDS
时间加权平均阈限值 ACGIH Threshold Limit Value-Time-Weighted Average TLV-TWA ppm v/v 800 Honeywell MSDS
允许暴露水平 OSHA Permissible Exposure Level PEL ppm v/v
工作环境暴露水平 AIHA Workplace Environmental Exposure Level WEEL ppm v/v 800 OARS
可接受暴露限值 Dupont Acceptable Exposure Limit AEL ppm v/v 300 http://www.gpo.gov/fdsys/pkg/FR-2012-08-10/html/2012-19688.htm
ASHRAE安全等级 ASHRAE Safety Group / /
嗅觉阈值 Odor Threshold / ppm v/v
大型水蚤半数作用浓度水生态毒性 Aquatic Toxicity of 48h Daphnia Magna Effective Concentration 50% EC50 mg/L 82 Honeywell MSDS
虹鳟鱼半数致死浓度水生态毒性 Aquatic Toxicity of 96h Rainbow Trout Lethal Concentration 50% LC50 mg/L 38 Honeywell MSDS
皮肤刺激或腐蚀
降解产物 Degradation Products Carbonyl halides ,CO,CO2,HF,HCl Honeywell MSDS