R365mfc

  性质 Properties Symbol Unit Value References
Basic Physical and Chemical Properties CAS注册号 CAS Registry Number CASRN / 406-58-6 Scifinder®
中文名称 Chemical Name / / 1,1,1,3,3-Pentafluorobutane
1,1,1,3,3-五氟丁烷
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英文名称 English Name / / HFC 365mfc,Solkane 365mfc Scifinder®
组成 Composition / / /
分子式 Molecular Formula / / C4H5F5 Scifinder®
结构式 Structure Formula / / CF3CH2CHF2CH3 Scifinder®
相对分子量 Molecular Weight MW / 148.07 Scifinder®
物理状态 Physical State / / liquid HARP MSDS
气味 Odor / / Colourless HARP MSDS
颜色 Color / / Ether-like HARP MSDS
熔点 Melting Point mp <-20
-32
HARP MSDS
维勒?克雷柯.高效绝热泡沫发泡剂Solkane 365mfc和Solkane 365/227
沸点 Boiling Point bp 32.5±8.0
40.2
40.1
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周鹏.环保型HFC-365mfc基聚氨酯硬泡材料
HARP MSDS
饱和蒸汽压 Saturated Vapor Pressure(25℃) Psat MPa 0.776
0.0433
0.04880
0.056764
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HARP MSDS
OSBORN MSDS
REFPROP 9.0
液体密度 Liquid Density(25℃) dl g/cm3 1.214±0.06
1.2578
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REFPROP 9.0
气体密度 Vapor Density(25℃, 101.325kPa) dg kg/m3 3.4964 REFPROP 9.0
挥发性 Volatility / wt%
蒸发速度 Evaporation Rate(CCl4=1) / /
Critical Properties 临界温度 Critical Temperature Tc 187.7 维勒?克雷柯.高效绝热泡沫发泡剂Solkane 365mfc和Solkane 365/227
临界压力 Critical Pressure Pc MPa 2.754 维勒?克雷柯.高效绝热泡沫发泡剂Solkane 365mfc和Solkane 365/227
临界体积 Critical Volume Vc cm3/mol
临界密度 Critical Density ρc kg/m3
临界压缩因子 Critical Compressibility Factor Zc /
液体压缩因子 Liquid Compressibility Factor Z / 0.0026975 REFPROP 9.0
气体压缩因子 Vapor Compressibility Factor Z / 0.96976 REFPROP 9.0
偏心因子 Acentric Factor ω / 0.38 REFPROP 9.0
Thermophysical Properties 液体焓 Liquid Enthalpy H kJ/kg 233.85 REFPROP 9.0
气体焓 Vapor Enthalpy H kJ/kg 429.15 REFPROP 9.0
液体熵 Liquid Entropy S kJ/kg·K 1.1184 REFPROP 9.0
气体熵 Vapor Entropy S kJ/kg·K 1.7735 REFPROP 9.0
生成焓 Enthalpy of Formation(25℃) ΔfHO kJ/mol
蒸发焓 Enthalpy of Vaporization ΔvH kJ/kg 3943.1041
3879.434
195.30
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维勒?克雷柯.高效绝热泡沫发泡剂Solkane 365mfc和Solkane 365/227
REFPROP 9.0
液体等压热容 Liquid Isobaric Heat Capacity(25℃) Cp kJ/kg·K 1.3768 REFPROP 9.0
气体等压热容 Vapor Isobaric Heat Capacity(25℃) Cp kJ/kg·K 1.0058 REFPROP 9.0
液体等容热容 Liquid Isochoric heat capacity(25℃) Cv kJ/kg·K 1.0340 REFPROP 9.0
气体等容热容 Vapor Isochoric heat capacity(25℃) Cv kJ/kg·K 0.93906 REFPROP 9.0
Solubility 偶极矩 Dipole Moment μ D
解离常数 Dissociation Constant
清洗能力 KB
水中溶解度 Solubility in Water(23℃) / ppm wt/wt 240
1700
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HARP MSDS
贝壳松脂丁醇值 Kauri-Butanol Value KB /
辛醇/水分配系数 Octanol/Water Partition Coefficient LogP / 1.784±0.412
1.6120
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HARP MSDS
Hildabrand溶解度参数 Hildabrand Solubility Parameter δ cal/ml
Other Properties 液体焦耳-汤姆逊系数 Liquid Joule-Thomson Coefficient JT ℃/MPa -0.28449 REFPROP 9.0
气体焦耳-汤姆逊系数 Vapor Joule-Thomson Coefficient JT ℃/MPa 35.607 REFPROP 9.0
液体粘度 Liquid Viscosity(25℃) η mPa·s 0.4 HARP MSDS
气体粘度 Vapor Viscosity(25℃) η mPa·s
液体导热系数 Liquid Thermal Conductivity(25℃) λ mW/m·K
气体导热系数 Vapor Thermal Conductivity(25℃) λ mW/m·K 10.6 周鹏.环保型HFC-365mfc基聚氨酯硬泡材料
液体介电常数 Liquid Dielectric Constant ε F/m
气体介电常数 Gas Dielectric Constant ε F/m
液体体积电阻系数 Liquid Volume Resistivity(1kHz) ρ Ω·cm
气体体积电阻系数 Gas Volume Resistivity(1kHz) ρ Ω·cm
表面张力 Surface Tension(25℃) γ mN/m 73.820 HARP MSDS
液体声速 Liquid Sound Velocity u m/s 726.67 REFPROP 9.0
气体声速 Vapor Sound Velocity u m/s 129.76 REFPROP 9.0
最低灭火浓度 Minimum Extinguishment Concentration MEC %
Atmospheric Effects 臭氧消耗潜能值 Ozone Depletion Potential ODP / 0
0
周鹏.环保型HFC-365mfc基聚氨酯硬泡材料
HARP MSDS
全球变暖潜能值 Global Warming Potential(100yr) GWP / 794
890
CRC Handbook of Chemistry and Physics(2010)
Slokane MSDS
大气寿命 Atmospheric Life / yr 8.6
16-19
CRC Handbook of Chemistry and Physics(2010)
Slokane MSDS
光化学臭氧合成潜能 photochemica lozone creation potential POCP /
全球温度潜势 global temperature change potential(100yr) GTP / 114 Global Warming Potentials and Radiative Efficiencies of Halocarbons and Related Compounds: A Comprehensive Review, Accepted for publication in Rev. Geophys
Flammability 闪点 Flash Point / -11.7±5.3
-25
<=-27
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OSBORN MSDS
Solkane MSDS
自燃点 Autoignition Point / 580
580
HARP MSDS
Solkane MSDS
燃烧下限 Lower Flammability Limit LFL %vol 3.6
3.6
HARP MSDS
Solkane MSDS
燃烧上限 Upper Flammability Limit UFL %vol 13.3
13.3
HARP MSDS
Solkane MSDS
燃烧热 Heat of Combustion HOC MJ/kg 12 维勒?克雷柯.高效绝热泡沫发泡剂Solkane 365mfc和Solkane 365/227
最小点火能 Minimum Ignition Energy MIE mJ 10.4 维勒?克雷柯.高效绝热泡沫发泡剂Solkane 365mfc和Solkane 365/227
燃烧速度 Burning Velocity Su cm/s
可燃浓度限值 ASHRAE Flammable Concentration Limit FCL ppm v/v
最大燃烧压力 Maximum Combustion Pressure 105Pa
最大燃烧压力上升速率 Maximum Rate of Pressure Increase During Combustion
Toxicity RTECS号 Registry of Toxic Effects of Chemical Substances® Number / /
接近致死浓度 Approximate Lethal Concentration ALC ppm v/v
半数致死浓度 Lethal Concentration 50% LC50 ppm v/v 100000 HARP MSDS
心脏致敏最低作用剂量 Cardiac Sensitization Lowest Observed Effect Level LOEL ppm v/v
心脏致敏最高无作用剂量 Cardiac Sensitization No Observed Effect Level NOEL ppm v/v
麻醉效应半数作用浓度 Anesthesia Effective Concentration 50% EC50 ppm v/v
麻醉效应最低作用剂量 Anesthesia Lowest Observed Effect Level LOEL ppm v/v
麻醉效应最高无作用剂量 Anesthesia No Observed Effect Level NOEL ppm v/v
28天亚急性吸入毒性 28 Days Subacute Inhalation Toxicity NOEL ppm v/v
90天亚慢性吸入毒性 90 Days Subchronic Inhalation Toxicity NOEL ppm v/v
一年长期吸入毒性 Long Term Inhalation Toxicity (12 month) NOEL ppm v/v
两年长期吸入毒性 Long Term Inhalation Toxicity (24 month) NOEL ppm v/v
立即威胁生命和健康浓度 NIOSH Immediately Dangerous to Life or Health IDLH ppm v/v
缺氧限值 ASHRAE Oxygen Deprivation Limit ODL ppm v/v
急性毒性暴露限值 ASHRAE Acute Toxicity Exposure Limit ATEL ppm v/v
制冷剂浓度限值 ASHRAE Refrigerant Concentration Limit RCL ppm v/v
职业接触限值 ASHRAE Occupational Exposure Limit OEL ppm v/v
时间加权平均阈限值 ACGIH Threshold Limit Value-Time-Weighted Average TLV-TWA ppm v/v
允许暴露水平 OSHA Permissible Exposure Level PEL ppm v/v
工作环境暴露水平 AIHA Workplace Environmental Exposure Level WEEL ppm v/v
可接受暴露限值 Dupont Acceptable Exposure Limit AEL ppm v/v 1000 HARP MSDS
ASHRAE安全等级 ASHRAE Safety Group / /
嗅觉阈值 Odor Threshold / ppm v/v
大型水蚤半数作用浓度水生态毒性 Aquatic Toxicity of 48h Daphnia Magna Effective Concentration 50% EC50 mg/L >200 HARP MSDS
虹鳟鱼半数致死浓度水生态毒性 Aquatic Toxicity of 96h Rainbow Trout Lethal Concentration 50% LC50 mg/L 200( Brachydanio rerio) HARP MSDS
皮肤刺激或腐蚀
降解产物 Degradation Products Gaseous Hydrogen fluoride (HF), Carbon monoxide HARP MSDS